Witherite - Cave-In-Rock, Illinois
Contributed by: Chris Clemens
Date: Apr 30th, 2026
Locality: Cave-in-Rock, Cave-In-Rock Mining Sub-District, Hardin County, Illinois, USA (See on Mindat)
Size: 71 x 49 x 75 mm
Weight: 302 g
Description:
Witherite is a relatively rare barium carbonate mineral that shows a blue/white, fluorescent response under shortwave and longwave UV. The historical fluorspar (fluorite) mines of Cave-In-Rock, Hardin County, Illinois, have produced specimens of witherite of exceptional quality. This specimen consists of a mass of large, twinned (pseudohexagonal) crystals of off-white witherite on a minimal matrix of unknown grey material. The witherite shows a similar fluorescent response under all UV wavelengths- glowing blue/white, slightly warmer under longwave. This specimen also shows green phosphorescence, most brightly following shortwave UV.
Originally posted by Chris Clemens on Nature's Rainbows in 2017.
Summary of luminescence responses:
Witherite (Mindat) (RRUFF)
- Fluorescence under Longwave (365nm LED) UV light: White
- Fluorescence under Shortwave (254nm Lamp/Mercury) UV light: White
- Afterglow after exposure to Shortwave (254nm Lamp/Mercury) UV light: Green



